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All you have to is use as Http / 1.1 301 (permanent redirect) from old URLs to the new ones to solve the problem.
HTH
One of my clients has had the cached page on google change twice over the weekend, they had a new site uploaded, then had it taken down the next day (don't ask me why). But the cached page changed as they upload the older version of the site.
I have had a new version of a site uploaded over 4 weeks ago, but it still hasn't had the cached paged updated. I have check the web logs and googlebots been seaching both sites over the weekend. Any ideas anyone why its cached the one site and not the other?
Both sites are of similar size and the URL's have been in use for well over 6 months.