Forum Moderators: Robert Charlton & goodroi
If you've got analytics of any kind, you should be able to get a list of URLs that are getting Google search traffic. Remove those URLs from your sitemap list and what remains is a good list to start your improvement campaign from. I would suggest that even if a page is in the index, if it's not getting any traffic then it's still very much worth a look.
Also, I've never seen a site of any significant size that is 100% indexed, so that's not a goal I even consider.