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New sites do not rank for homepage I notice...
If you go to Google.co.uk and use the site: operator and select 'pages from the UK' option, do you get any results?
Okay, it looks like most of my pages are included in the "uk pages" searches, it just happened to be this one search that listed an inner page for worldwide but not for UK only. As far as I can tell, there are only 12 pages that this is occuring for ... so now I'm even more confused, how can 12 pages of my site not rank in UK only but the rest (103 pages) rank just fine?