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Writing pages in xml by hand doesnt make alot of sense at the moment (though I dont find it significantly different than writing xhtml): but in the world of generated content it does in many instances. Shopgal: you have good ranking AND your page is written in xml 1.0, not xhtml, right? That is interesting...
And yes, XML's time has already come in many circles, and when IE supports it fully, you will see many xml pages showing up. Until then, yeah, its completely impractical from a business standpoint (unless your market is all Linux users).
Its gonna happen... I just want to be fully versed in the technology when the time comes.