Beginning ASP.NET 4 in C# and VB by Imar Spaanjaars
But if you're new to this, I'd scrap .NET and go to PHP. I am forced to use .net for work, but I don't think it will be around in 5 years... Just look at the amount of posts in the PHP forum compared to here. It's a ghost town here. From what I can see you're going to get a lot of white haired execs pushing .net, while the youth is all PHP.