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I did try it on my PC though I'm running IIS and the webmatrix webserver seems to be interegrated with it. So I couldn't tell you how it perfoms on a PC without IIS.
On another note if you do install webmatrix i'd recommend changing the default view (tools-->preferences-->web editing) to "source" rather than "design", as in design view web matrix will try and re-write all your HTML which can be a pain.