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(The problem was described by another user but no one came up with an answer for it, that is why I am reposting it now.)
I did a straight forward installation of VB.NET Standard edition on an XP machine.
Thank you for the help.
I must be a configuration setting I think maybe in IIS? It doesn't seem to recognise .aspx files?
If you exhust all poss' then have a scan through MS's website and see if there is anything on there. It maybe like php where you have to grab a config file and run it at startup to get IIS to recognise and use it correctly.