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If you only want to give one cell a border, for example, follow the above example and make the border colour the same as the background colour. Then go to the cell you want a border on and change the border colour to the colour you want.
btw, worth getting the books for the version of dreamweaver and giving them a quick once over, covers the basics, if this is not possible, the lessons (tutorials) in HELP, cover a reasonable amount of the basics.
But don't forget to hand code. There are times when it's easier to just go in and hand code it, because DW has a hard time with certain things here and there.