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Any ideas would be MUCH appreciated!
As far as I am aware there is no way to get this information easily i.e. no export feature.
When Office XP launched, I spoke to one of the Senior Tech Support people here in Australia because I wanted the ability to be able to remove some bad email addresses from the auto complete. He checked with the developers and there was no way to do so - no clear history like there is with IE.
Perhaps you can get start "afresh" and allow outlook to copy anyone he replies to to his contacts folder automatically. Just a thought.