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TV/VCR: 25 interlaced frames per second at a resolution of 720 x 576 (PAL) (29.97 frames at 720 x 486 for NTSC)
Webcam: ~20 full (progressive) frames per second at 640 x 480 resolution
The electronics you need to develop to transform those two would be quite bulky and expensive. Apart from that, the CCD's used in webcams are fare from the quality level used for TV (even for NTSC).