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The .htaccess is as follows:
ErrorDocument 404 /404.htm
But where exactly should the file be? I have tried it in many places with no luck.
In the httpd.conf the following is set :
Allow from all
#LoadModule rewrite_module modules/mod_rewrite.so
Is there anything else I should be doing?
Your LoadModule rewrite_module line is commented out, so remove the "#" from the beginning.
You'll also need to enable certain AllowOverride settings and Options to allow mod_rewrite to work.
See this thread on setting up mod_rewrite [webmasterworld.com] for more info.