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That may show you some error message or similar. When you first
connect to a remote host via SSH, you'll see something like :
Host key not found from the list of known hosts.
Are you sure you want to continue connecting (yes/no)?
Just maybe (long shot, I know) Dreamweaver is getting stuck
at that point. Logging in manually would allow you to enter
"yes (only needed once).
If this isn't it at all, logging in manually may still give you clues/info to work with.