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caribguy - 8:46 pm on Sep 20, 2009 (gmt 0)
My guess would be that the learning curve from PHP to Python is fairly easy.
You might want to look at web frameworks, rather than complete CMS implementations. The ones that I'm most familiar with utilize Python as a scripting language, my favorite is Zope [zope2.zope.org]. Other Python frameworks include Ruby-on-Rails, Django, Turbogears...